SHERWIN-WILLIAMS -- 1505 WHITE, KRYLON HIGH HEAT RESISTANT PAINTS -- 8010-01-141-3949
===================== Product Identification ===================== Product ID:1505 WHITE, KRYLON HIGH HEAT RESISTANT PAINTS MSDS Date:09/01/1996 FSC:8010 NIIN:01-141-3949 === Responsible Party === Company Name:SHERWIN-WILLIAMS Address:31500 SOLON RD City:SOLON State:OH ZIP:44139 Country:US Info Phone Num:800-247-3270 Emergency Phone Num:216-566-2917 CAGE:DO642 === Contractor Identification === Company Name:KRYLON INDUSTRIAL Box:UNKNOW CAGE:KRYLX Company Name:SHERWIN-WILLIAMS CO THE SPECIALTY DIV. Address:6830 COCHRAN RD. Box:6709 City:SOLON State:OH ZIP:44139-3908 Phone:216-292-7400 CAGE:DO642 ============= Composition/Information on Ingredients ============= Ingred Name:PROPANE. VP:760. CAS:74-98-6 RTECS #:TX2275000 Fraction by Wt: 18% OSHA PEL:1000 PPM ACGIH TLV:ASPHYXIANT Ingred Name:TOLUENE (SARA 313) (CERCLA). VP:22. CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 28% OSHA PEL:200 PPM ACGIH TLV:50 PPM, S EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:XYLENE (SARA 313) (CERCLA). VP:5.9. CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 2% OSHA PEL:100 PPM ACGIH TLV:100 PPM;150 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:METHANOL; (METHYL ALCOHOL) (SARA 313) (CERCLA). VP:92. CAS:67-56-1 RTECS #:PC1400000 Fraction by Wt: 3% OSHA PEL:200 PPM, S ACGIH TLV:200 PPM;250 STEL, S EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ACETONE (SARA 313) (CERCLA). VP:180. CAS:67-64-1 RTECS #:AL3150000 Fraction by Wt: 34% OSHA PEL:1000 PPM ACGIH TLV:750 PPM;1000 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE) CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 7.6% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:VOLATILE ORGANIC COMPOUNDS (BAAQMD RULE 49): 51.8% (WT); 3.44 LBS/GAL. RTECS #:9999999VO Ingred Name:EFTS OF OVEREXP:SUCH EXPOS LEVELS ARE NOT ATTAINABLE IN WORKPLACE. RPTS HAVE ASSOC RPTD & PRLNG OVEREXP TO SOLVS (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:W/PERM BRAIN & NERV SYS DMG. INTENTIONAL MISUSE BY DELIB CONC & INHAL CONTENTS CAN BE HARMFUL/FATAL. (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:WARNING:THESE PRODS CNTN CHEM(S) KNOWN TO STATE OF CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS/OTHER REPRO (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:HARM. NOTE:TOLUENE APPEARS ON NAVY LIST OF OCCUP CHEM REPROS HAZS. SEEK CONSULTATION FROM APPROP HLTH (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11:PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS INFO . RTECS #:9999999ZZ Ingred Name:OTHER PREC:CONSULT NFPA CODE. CONTENTS UNDER PRESS. DO NOT PUNCTURE, INCIN/EXPOSE TO TEMP >120F. HEAT FROM (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:SUNLIGHT, RADIATORS, STOVES, HOT WATER & OTHER HEAT SOURCES COULD CAUSE CNTNR TO BURST. DO NOT TAKE (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14:INTERNALLY. KEEP OUT OF REACH OF CHILDREN. ADDN OF REDUCERS/OTHER ADDITIVES TO THIS PROD MAY (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15:SUBSTANTIALLY ALTER COMPOSITION & HAZS OF PROD. USE ONLY W/ADEQ VENT. AVOID BRTHG VAP & SPRAY MIST. AVOID(ING 17) RTECS #:9999999ZZ Ingred Name:ING 16:CONT W/SKIN & EYES. THESE COATINGS MAY CONTAIN MATLS CLASSIFIED AS NUISANCE PARTICULATES WHICH MAY BE (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17:PRESENT AT HAZ LEVELS ONLY DURING SANDING/ABRADING OF DRIED FILM. IF NO SPECIFIC DUSTS ARE LISTED, APPLIC(ING 19) RTECS #:9999999ZZ Ingred Name:ING 18:LIMS FOR NUISANCE DUSTS ARE ACGIH TLV 10 MG/M3 (TDUST), OSHA PEL 15 MG/M3 (TDUST), 5 MG/M3 (RESPIRABLE FRACTION). RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EXPOS MAY BE BY INHAL &/OR SKIN/EYE CONT, DEPENDING ON CNDTNS OF USE. TO MIN EXPOS, FOLLOW RECS FOR PROPER USE, VENT & PPE. ACUTE:IRRIT OF EYES, SKIN & RESP SYS. MAY CAUSE NERV SYS DEPRESS. EXTREME OV EREXP MAY RSLT IN UNCON & POSS DEATH. HDCH, DIZZ, NAUS & LOSS OF COORD ARE INDICATIONS OF EXCESSIVE (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:EXPOS TO VAPS/SPRAY MISTS. REDNESS & ITCH/BURNING SENSATION MAY INDICATE EYE/EXCESSIVE SKIN EXPOS. CHRONIC:PRLNG OVEREXP TO SOLV INGS MAY CAUSE ADVERSE EFTS TO LIVER, URINARY, BLOOD-FORMING, CARDIOVASCULAR & REPRO SYSTEMS. RATS EXPOS TO TITANIUM DIOXIDE DUST AT 250 MG/M3 DEVEL LUNG CANCER, HOWEVER, (ING 8) Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM & QUIET. SKIN:WASH AFFECTED AREA THOROUGHLY W/SOAP & WATER. REMOVE CONTAMINATED CLOHTING & LAUNDER BEFORE RE-USE. EYES:FLUSH W/LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. INGEST:GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:<0F,<-18C Lower Limits:1% Upper Limits:36.5% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . WATER SPRAY MAY BE INEFT. IF WATER IS USED, FOG NOZZ ARE PREF. WATER MAY BE USED TO COOL CLSD CNTNRS TO (SUPDAT) Unusual Fire/Explosion Hazard:EXTREMELY FLAMM. ISOLATE FROM HEAT, ELEC EQUIP, SPKS & OPEN FLAME. CLSD CNTNRS MAY EXPLODE WHEN EXPOS TO EXTREME HEAT. APPLICATION TO HOT SURFS REQS (SUPP DATA) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE & REMOVE W/INERT ABSORBENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:NFPA CODE 30B - LEVEL 3 AEROSOLS. CONTENTS ARE EXTREMELY FLAMM. KEEP AWAY FROM HEAT, SPKS & OPEN FLAME. USE APPRVD BONDING & GROUNDING PROCS. Other Precautions:VAPS WILL ACCUM READILY & IGNITE EXPLOSIVELY. DURING USE & UNTIL ALL VAPS ARE GONE:KEEP AREA VENTED; DO NOT SMOKE; EXTING ALL FLAMES, PILOT LIGHTS & HEATERS; TURN OFF STOVES, ELEC TOOLS & APPLIANCES & ANY OTHER SOURCES OF IGNIT. (ING 13) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW APPLIC LIMS BY VENT, WEAR NIOSH APPRVD PROPERLY FITTED ORGANIC VAPOR/PARTICULATE RESP FOR PROT AGAINST INGS. WHEN SANDING/ABRADING DRIED FILM, WEAR A NIOSH APPRVD DUST/MIST RESP FOR PROT (SUPDAT) Ventilation:LOC EXHST PREF. GEN EXHST ACCEPT IF EXPOS TO INGS IS MAINTAINED BELOW APPLIC EXPOS LIMS. REFER TO OSHA STDS (SUPP DATA) Protective Gloves:CHEMICAL RESISTANT GLOVES. Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS . Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . Work Hygienic Practices:WASH HANDS AFTER USING. Supplemental Safety and Health FIRE FIGHT PROC:PVNT PRESS BUILD-UP & POSS AUTOIGNIT/EXPLO WHEN EXPOS TO EXTREME HEAT. RESP PROT:AGAINST NON-VOLAT INGS. VENT:1910.94, 1910.107, 1910.108. EXPLO HAZ:SPECIAL PRECS. DURING EMER CNDTNS O VEREXP TO DECOMP PRODS MAY CAUSE HLTH HAZ. SYMPS MAY NOT BE IMMED APPARENT. OBTAIN MED ATTN. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:<395F,<202C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Spec Gravity:0.80 Evaporation Rate & Reference:FASTER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:BY FIRE:CARBON DIOXIDE, CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE FROM THIS PRODUCT MAY BE HAZ AS DEFINED UNDER RCRA (40 CFR 261). WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE APPLIC EPA HAZ WASTE NUMBERS. DO NOT INCINERATE. DEPRESSURIZE CNTNR. DISPOSE O F I/A/W FED, STATE & LOC REGS REGARDINGPOLLUTION. 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